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We have studied the thermotropic and lyotropic phase behaviour of different monoalkyl glycosides using polarizing microscopy, differential scanning calorimetry and rheology. The dependence of the liquid crystal transition temperature and mesophase formation on the chain length of the hydrophobic tail has been studied. The melting transition for each of the dry alkyl-glycosides corresponds White pages ellicottville Germantown one or two solid—solid transitions, a solid—liquid crystalline transition and a liquid crystalline—liquid isotropic transition. The lyotropic behaviour follows the classical pattern established for the surfactants.

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